Look at these examples:

Je mange à deux heures de l'après-midi. I eat at 2pm.

Je vais manger à huit heures.I will eat at eight o'clock.

Nous allons partir à midi.We're going to leave at midday.
 

Notice that you use à + heure to say at what time something happens.

 
See also En vs dans (prepositions of time)
and After / before versus in front of / behind (prepositions of time and place)

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Examples and resources

Je vais manger à huit heures.I will eat at eight o'clock.
Nous allons partir à midi.We're going to leave at midday.
Je mange à deux heures de l'après-midi. I eat at 2pm.
La soirée commence à sept heures et demie.The party starts at seven thirty.
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